Some forms of silica, known as colloidal, or non-reactive, are not removed by a mineralization. Hot,alkaline boiler water dissolves the colloidal material, forming simple silicates that are similar to those that enter the boiler in a soluble form. As such, they can form deposits on tube surfaces and volatilize into the steam.
Hence feed water is to be very pure for high pressure boilers. This, in turn, necessitates high purity for make-up water. Demineralisation can only produce acceptable make-up quality for high pressure boilers of the order of specific electrical conductivity less than 0.5 mmho/cm with hardness completely removed and silica less than 0.02 ppm. When
This object is achieved in accordance with the invention by a process for exfoliating organically modified sheet silicates, in which: a resin component and the sheet silicate are mixed to give a free-flowing mixture; the mixture is subjected to high-pressure dispersion at a pressure of more than 50 bar and a temperature of more than 0°C.
in case of an explosion or other event rendering a boiler or pressure vessel unsafe to return to operation, notice shall be given immediatly to the code official. no boiler unfired pressure vessel nor any parts shall be removed or disturbed before an inspection is made by a city inspector, except necessary to prevent injury.
May 05, 2015 · Boiler Chemistry Control and Treatment of Feed Water. Silica from CW is another damaging factor as it deposits on turbine. Silica needs to be controlled at DM plant also. The percentage of impurity allowed in boiler water/steam is function of boiler operating pressure, so, more critical for high pressure boilers.
and vapour phases in a boiler. As the temperature and pressure are increased, more silica becomes present in the steam. In high pressure boilers, therefore, silica is appreciably concentrated in the steam and this is when 'carry-over' may occur, being deposited later, on the superheaters or turbine blades. Silica entering a high pressure boiler can concentrate very quickly. An impurity
silica etc. into the boiler and turbine. These substances deposit out on the heat transfer surfaces and turbine blades. Accelerated corrosion in many regions of high pressure boilers is known to be brought about by concentration of corrosive substances (chlorides, sulphates, hydroxides and phosphates) by boiling. The
Organic chemicals (typically hydrocarbons) with a high vapor pressure (low saturation temperature) at room temperature. Windbox A chamber below a stoker grate or surrounding a burner, through which pressurized combustion air is introduced to a boiler furnace.
all dissolved solids for higher-pressure boilers that have tighter restrictions on boiler chemistry. Positively charged ions (cations) such as sodium, calcium, magnesium, and iron are exchanged for hydrogen ions, and negatively charged ions (anions) such as chloride, sulfate, carbonate, and silica are exchanged by hydroxide ions. Instead of salt,
Magnesium: Magnesium usually forms hydroxides or silicates in boiler water, which are desirable types of sludge. If boiler water alkalinity is low, undesirable magnesium phosphate often forms which is sticky and scale forming. In cooling water system, magnesium only precipitates when pH is over 10.0.
Such deposits may contain calcium, magnesium, phosphate, iron, and silica. A tenacious form of boiler scale results when calcium precipitates in the form of calcium carbonate. Boiler sludge is a deposit that forms when suspended materials present in the boiler water settle on, or adhere to, hot boiler tubes or other surfaces.
because it does not passivate low pressure boilers, where sulfite is most often used. Passivation can be accomplished in high pressure boilers, but high dosages of sulfite are needed. Sulfite is commonly supplied as sodium sulfite, Na 2SO 3; sodium bisulfite, NaHSO 3; ammonium sulfite, (NH 4) 2SO 3; or sodium metabisulfite, Na 2S 2O 5.
High pH in the boiler water will reduce silica carryover from the boiler water. Monitor the steam because: •Precipitation of silica forms silicate deposits on the cold end of the turbine that are not water soluble and are very difficult to remove. The deposits may cause superheater failures or turbine failures.
Silica is one of the major scale forming elements in boiler water chemical regime (WCR) of thermal power industry. Carryover of silica is also another serious problem, particularly in high pressure and critical pressure boilers, Hence, generally the medium-pressure, high-pressure and critical-pressure boilers are equipped with super heaters and turbine. Silica in steam can result from mechanical carryover
2.0. Boiler Classifications Based on the pressure rating, boilers can be classified as high pressure, medium pressure and low pressure boilers. Generally, boilers operating above 22 Kg/cm 2 are considered as high pressure boilers. Those operating below 10 kg/cm 2 are considered as low pressure boilers. Medium pressure boilers are those operating
It can form hard scale in boilers and cooling systems with resulting mechanical and heat transfer problems or pass over with steam at high pressures to form glassy deposits on turbine blades. Iron occurs in concentrations upto about 15 ppm. Associated problems can be more widespread than those from silica. Most common form is ferrous bicarbonate.
Nov 01, 2017 · The salts dissolve in water to form an Water Treatment for High Pressure Boilers in Water Treatment for High Pressure Boilers manganese and silica have the same effect as hardness is Water Treatment for High Pressure Boilers Make up Water Scaling in boilers – Lenntech and prevention of scaling in boilers,
In high pressure boilers, any chemical contaminants present in the steam can quickly build upvin the boiler drum and can be carried over in the steam to the turbine.
form in boilers having high silica feedwater. Calcium and magnesium ions will form silicate sludges, which are gelatinous and readily adherent. When silicate deposits are baked onto the boiler tubes, a very highly insulating crust is formed with potentially damaging consequences. In boilers operating above 600 psig, silica will steam distill
Aug 14, 2018 · While this is not a concern with most common minerals at pressures less than 1,000 psi, vaporous carryover of silica can occur at pressures as low as 400 psig. Consequently, boiler water silica level must be carefully limited in higher pressure systems, especially if turbines are present. Prevention of Carryover
Silica is a problem for high pressure boil- ers. It exhibits enough volatility that high pressure boilers will have silica carry over to the vapor partition. When the steam pressure is reduced in the tur- bines, the silica will precipitate on the blades as a glassy deposit which re- duces efficiency.
The emulsion is broken and the produced water is treated for reuse in the steam generators. This produced water has a much lower purity than water commonly used to feed conventional boiler systems. High concentrations of silica and soluble organic species are present. Ammonia and sulfide ion are also regularly present.
Silica in boiler feedwater precipitates and forms a hard, glossy coating on the internal surfaces. In the feedwater of high-pressure boilers, such as those used in electric generating plants, a certain amount of silica vaporizes under the influence of high pressure and temperature.
The presence of silica in boiler water can rise to formation of bard silicate scales. It can also associate with calcium and magnesium salts, forming calcium and magnesium silicates of very low thermal conductivity.
Nov 01, 2017 · Water Treatment for High Pressure Boilers in Sugar – unfccc cdm Iron, manganese and silica have the same effect as hardness is producing deposits in stains, it spells trouble in industrial and municipal supplies-increasingly with Water treatment is very important in high pressure boilers to protect the
Carryover. Carryover is any contaminant that leaves the power station boiler within the steam that flows into the turbine. Silica is the most common contaminant. It volatilizes -- becomes a gas -- at the high pressures and temperatures within the boiler. It also forms a colloidal solution -- a stable suspension of silica particles -- with water.
Scale Formation In The Boiler - Silica is found in most waters, casting sand and welding flux. In low-pressure boiler Si03 combines with ca and mg to form calcium and magnesium silicates, which can precipitate and form hard scale. In high-pressure boiler silica volatilizes with steam and deposits in turbine blades causing severe loss in
Silica Scaling in Boilers. It has been demonstrated that for any given set of boiler conditions using demineralized or evaporated quality make up water, silica is distributed between the boiler water and the stream in a definite ratio. This ratio depends on water pressure and boiler water pH as shown in the picture on the right.
High temperatures in the boiler water reduce the solubility of calcium sulphate and tend to make it precipitate out directly on the boiler metal as scale. Consequently calcium sulphate must be reacted upon chemically to cause a precipitate to form in the water where it can be conditioned and removed by blow-down.
(TDS or conductivity, pH, Silica and Phosphates concentration) within This type of blow down is common in high-pressure boilers Blowdown Get a qoute Boiler Water Chemistry
Silicates are forming silicate deposits, while the present a kind of volatility. So an amount of silica escapes to the steam, and when steam condenses, it is deposited as pure solid silica.. For High pressure boilers, we suggest you to use the relationship: NCmax=Max SiO 2 (boiler)/SiO2(MU)
Sodium sulphite is used for low pressure boiler. Amine is preferred in high pressure boiler because it does not add to TDS, unlike Sodium sulphite. Effect of pH Both high and low pH can cause corrosion in boiler. In acidic range the protective layer of magnetite is not able to form and it cause corrosion. In very high pH range the protective layer of
The following are specified limit for high pressure boiler from different organization:- ASME Guidelines for Water Quality in Modern Industrial Water Tube Boilers for Reliable Continuous Operation:- Boiler Feed Water Boiler Water. Drum Pressure (psi) Iron (ppm Fe) Copper (ppm Cu) Total. Hardness. (ppm CaCO3) Silica (ppm SiO. 2) Total Alkalinity**.
Mar 26, 2018 · Boilers that generate steam to power turbines require high-pressure boilers and therefore more complex feed water treatment system to remove as many impurities as possible. When steam is produced inside the boiler, the water particles collect and condense, then are recycled and used as part of the boiler feed water.
Sep 26, 2016 · Ion exchange softening. When pretreating boiler feed water, if there’s high hardness complexed with bicarbonates, sulphates, chlorides, or nitrates, a softening resin can be used. This procedure uses a strong acid cation exchange process, whereby resin is charged with a sodium ion, and as the hardness comes through,
means a boiler used heating water or liquid to a pressure exceeding 160 psi (1100 kpa) or to a temp. exceeding 250 degrees F (121 degrees C). 4.13.6 posting permit the permit holder or permit holders agent shall post the permit in a conspicuous place on the premises as directed by the code official.
Sep 26, 2016 · Silica: if not removed to low levels, especially in high-pressure boilers, silica can cause extremely hard scaling Calcium: can cause scaling in several forms depending on the chemistry of the boiler feed water (e.g. calcium silicate, calcium phosphate, etc.)
any water carryover is occurring is to measure the conductivity of the steam or of the. steam condensate. If you detect less than 25 micromhos conductivity in the condensate, then carryover is probably insignificant.
Boiler water treatment. These chemicals react with calcium and magnesium compounds in the feed water. Sodium silicate is used to react selectively with magnesium hardness. Calcium bicarbonate entering with the feed water is broken down at boiler temperatures or reacts with caustic soda to form calcium carbonate.
Steam and water analysis system. Steam and water analysis system ( SWAS) is a system dedicated to the analysis of steam or water. In power stations, it is usually used to analyze boiler steam and water to ensure the water used to generate electricity is clean from impurities which can cause corrosion to any metallic surface, such as in boiler and turbine.